I also have Skype Premium and although I don't see ads on my PC or Mac, I do on my iPhone, and there is no way to turn them off. This is double-dipping by Microsoft: we pay a subscription AND we have to look at pop-up ads. Does anyone have a solution?
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Just to double check: You are using the same account to sign in on Mac and iPhone, right?
I am not getting the ads on my iPhone anymore. I logged off on my iPhone. I changed my Skype password on my Mac. Then logged back in with the new Skype password. I think I had been logged in on my iPhone with my Microsoft account, and maybe that's why I was getting the ads. It's strange that the Microsoft account might not have recognized my Premium Skype account.
Same problem here. I'm running latest version of Win8.1 with Skype Desktop (find the App terribly annoying, sorry) latest version. Upgraded to Premium a while ago, but still getting ads. I've logged off and on with both Windows and Skype accounts, but the ads keep coming. Anybody found a solution?